Preparation and Study of 3-Coordinate Mixed-Ligand Copper(I) Compounds - Molecular and Crystal-Structure of (Tricyclohexylphosphine)(2-Thioxohexamethyleneimine)Copper(I) Iodide
| dc.contributor.author | Akrivos, P. D. | en |
| dc.contributor.author | Kapsomenos, G. | en |
| dc.contributor.author | Karagiannidis, P. | en |
| dc.contributor.author | Skoulika, S. | en |
| dc.contributor.author | Aubry, A. | en |
| dc.date.accessioned | 2015-11-24T16:45:23Z | |
| dc.date.available | 2015-11-24T16:45:23Z | |
| dc.identifier.issn | 0020-1693 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8924 | |
| dc.rights | Default Licence | - |
| dc.subject | cu(i) complexes | en |
| dc.subject | heterocyclic thiones | en |
| dc.subject | tolylphosphine | en |
| dc.subject | photolysis | en |
| dc.subject | models | en |
| dc.subject | series | en |
| dc.title | Preparation and Study of 3-Coordinate Mixed-Ligand Copper(I) Compounds - Molecular and Crystal-Structure of (Tricyclohexylphosphine)(2-Thioxohexamethyleneimine)Copper(I) Iodide | en |
| heal.abstract | A group of mixed ligand copper(I) coordination compounds with the saturated heterocyclic thione 2-thioxohexamethyleneimine (omega-thiocaprolactam, tclH) and tricyclohexylphosphine (Pcy3) is prepared and studied. The concerted steric effects of the two bulky ligands result in the formation of three-coordinate copper(I) complexes. The iodo compound is studied by single crystal X-ray diffraction and is shown to crystallize in the P2(1)/n space group. Four monomer units with no apparent close contacts between them are present in the unit cell, the dimensions of which are a = 10.306(2), b = 15.937(2), c = 16.774(2) angstrom, and beta = 100.06(1)-degrees. The compound is trigonal planar with the Cu-S, Cu-P and Cu-I bonds equal to 2.243(2), 2.241(2) and 2.564(1) angstrom respectively. A computational study is also carried out aiming at the understanding of the factors influencing planar or pyramidal conformation in three-coordinate CuLL'L" compounds. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.secondary | <Go to ISI>://A1992KC62600013 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S0020169300853530/1-s2.0-S0020169300853530-main.pdf?_tid=df7f80e75c4164e02be6c9a4343f8327&acdnat=1333040501_2e5a6c78d20f0ed0b90f72c61dda4f2d | - |
| heal.journalName | Inorganica Chimica Acta | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 1992 | - |
| heal.publisher | Elsevier | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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