New Antimony(III) Bromide Complexes with Thioamides: Synthesis, Characterization, and Cytostatic Properties

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dc.contributor.authorOzturk, I. I.en
dc.contributor.authorHadjikakou, S. K.en
dc.contributor.authorHadjiliadis, N.en
dc.contributor.authorKourkoumelis, N.en
dc.contributor.authorKubicki, M.en
dc.contributor.authorTasiopoulos, A. J.en
dc.contributor.authorScleiman, H.en
dc.contributor.authorBarsan, M. M.en
dc.contributor.authorButler, I. S.en
dc.contributor.authorBalzarini, J.en
dc.date.accessioned2015-11-24T16:42:35Z
dc.date.available2015-11-24T16:42:35Z
dc.identifier.issn0020-1669-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8571
dc.rightsDefault Licence-
dc.subjectmolecular-orbital methodsen
dc.subjectcrystal-structuresen
dc.subjectbasis setsen
dc.subjectdensityen
dc.subjectexchangeen
dc.subjectligandsen
dc.subjectseriesen
dc.titleNew Antimony(III) Bromide Complexes with Thioamides: Synthesis, Characterization, and Cytostatic Propertiesen
heal.abstractNew antimony(III) bromide complexes with the heterocyclic thioamides, thiourea (TU), 2-mercapto-1-methylimidazole (MMI), 2-mercapto-benzimidazole (MBZIM), 2-mercapto-5-methyl-benzimidazole (MMBZIM), 5-ethoxy-2-mercapto-benzimidazole (EtMBZIM), 2-mercapto-3,4,5,6-tetrahydro-pyrimidine (tHPMT), 2-mercaptopyridine (PYT), 2-mercapto-thiazolidine (MTZD), 3-methyl-2-mercaptobenzothiazole (MMBZT), and 2-mercaptopyrimidine (PMTH) of formulas [SbBr(3)(TU)(2)] (1), [SbBr(3)(MMI)(2)] (2), {[SbBr(2)(MBZIM)(4)](+) [Br](-) H(2)O} (3), {[SbBr(2)(mu(2)-Br)(MMBZIM)(2)](2)} (4), {[SbBr(2)(mu(2)-Br)(EtMBZIM)(2)](2) MeOH} (5), {[SbBr(3)(mu(2)- S-tHPMT)(tHPMT)](n)} (6), ([SbBr(2)(mu(2)-Br)(PYT)(2))(n)} (7), {[SbBr(2)(mu(2)-Br)(MTZD)(2)](n)} (8), [SbBr(3)(MMBZT)(2)] (9), and {[SbBr(5)](2-) [(PMTH(2)(+))(2)]} (10) have been synthesized and characterized by elemental analysis, conductivity measurements, FTIR spectroscopy, FT-Raman spectroscopy, TG-DTA analysis, and X-ray powder diffraction. The crystal structures of 3, 4, 5, 6, 7, 8, and 10 were also determined by X-ray diffraction. In 3, four sulfur atoms from thione ligands and two bromide ions form an octahedral (O(h)) cationic [SbS(4)Br(2)](+) species in which the two bromide anions lie at axial positions. A third bromide counteranion neutralizes the whole complex. 4 and 5 are dimers, whereas 6, 7 and 8 are polymers, built up by monomeric units of square pyramidal (SP) geometry around the metal center, which were formed by two sulfur atoms of thioamide ligands and three bromide ions. Finally, 10 is ionic salt containing 1D polymeric network of {[SbBr(5)](2-)}(n) anions and -[(PMTH(2)(+))(2)] counter cations. in the lattice. The complexes showed mostly a moderate cytostatic activity against a variety of tumor cell lines.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDoi 10.1021/Ic8019205-
heal.identifier.secondary<Go to ISI>://000263667700053-
heal.identifier.secondaryhttp://pubs.acs.org/doi/pdfplus/10.1021/ic8019205-
heal.journalNameInorg Chemen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2009-
heal.publisherAmerican Chemical Societyen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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