Structural, electron paramagnetic resonance and electron spin echo envelope modulation studies of oxovanadium(IV)-amidate compounds containing monoanionic axial ligands: effect on the V-51-hyperfine coupling constants
| dc.contributor.author | Tolis, E. J. | en |
| dc.contributor.author | Soulti, K. D. | en |
| dc.contributor.author | Raptopoulou, C. P. | en |
| dc.contributor.author | Terzis, A. | en |
| dc.contributor.author | Deligiannakis, Y. | en |
| dc.contributor.author | Kabanos, T. A. | en |
| dc.date.accessioned | 2015-11-24T16:48:08Z | |
| dc.date.available | 2015-11-24T16:48:08Z | |
| dc.identifier.issn | 1359-7345 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9286 | |
| dc.rights | Default Licence | - |
| dc.subject | spectroscopy | en |
| dc.subject | vo2+ | en |
| dc.subject | complexes | en |
| dc.subject | site | en |
| dc.title | Structural, electron paramagnetic resonance and electron spin echo envelope modulation studies of oxovanadium(IV)-amidate compounds containing monoanionic axial ligands: effect on the V-51-hyperfine coupling constants | en |
| heal.abstract | Reaction of the amidate ligand N-{2-[(2-pyridylmethylene)amino]phenyl}pyridine-2-carboxamide (Hcapca) with [VOCl2(thf)(2)] and MeONa in 1 : 1 : 1 molar ratio in MeCN affords the compound trans-[VOCl(capca)] 1, while reaction of 1 with NEt4NCS, MeCO2NHEt3 and imidazole yields the complexes trans-[VO(NCS)(capca)] 2, trans-[VO(Me-CO2)(capca)] 3 and trans-[VO(im)(capca)](-) 4 respectively; the X-ray crystal structure of 1 is reported; Cw EPR studies of compounds 1-3 reveal a novel phenomenon of the reduction of their A(z) components by ca. 10% compared to N-4 reference compounds. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.secondary | <Go to ISI>://000086373000037 | - |
| heal.journalName | Chemical Communications | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2000 | - |
| heal.publisher | Royal Society of Chemistry | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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