Interactions of trivalent lanthanide cations with tetradentate Schiff bases: New lanthanide(III) complexes from (1S,2S,(NE)-E-1,(NE)-E-2)-N,N '-bis(pyridin-2-ylmethylene)cyclohexane-1,2-diamine

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dc.contributor.authorTsiouri, M.en
dc.contributor.authorHadjiliadis, N.en
dc.contributor.authorArslan, T.en
dc.contributor.authorKariuki, B. M.en
dc.contributor.authorPlakatouras, J. C.en
dc.date.accessioned2015-11-24T16:40:22Z
dc.date.available2015-11-24T16:40:22Z
dc.identifier.issn1387-7003-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8267
dc.rightsDefault Licence-
dc.subjectcrystal structureen
dc.subjectlanthanide complexesen
dc.subjectschiff basesen
dc.subjecttetradentate ligandsen
dc.subject6-nitrogen-donor macrocyclic liganden
dc.subjectray crystal-structureen
dc.subjecteuropium(iii)en
dc.subjectyttrium(iii)en
dc.subjectneodymium(iii)en
dc.subjectionsen
dc.titleInteractions of trivalent lanthanide cations with tetradentate Schiff bases: New lanthanide(III) complexes from (1S,2S,(NE)-E-1,(NE)-E-2)-N,N '-bis(pyridin-2-ylmethylene)cyclohexane-1,2-diamineen
heal.abstractThe novel lanthanide(III) complexes [Ln(NO3)(3)(MeOH)L] (Ln = La 1, Pr 2), and [Ln(NO3)(3)L] . MeOH (Ln = Sm 3, Gd 4) where L = N,N'-bis(pyridin-2-ylmethylene)cyclohexane-1,2-diamine, have been obtained by direct reaction of the Schiff base ligand and the corresponding hydrated lanthanide(III) nitrates in methanol. All complexes were characterized spectroscopically and thermogravimetrically. Complexes 2 and 3 were also characterized with crystallographic studies. In the molecular structure of 2, Pr(III) is surrounded by all four nitrogen atoms of the Schiff base and seven oxygen atoms belonging to three bidentate chelating nitrato ligands and a coordinated methanol molecule, while in 3, Sm(III) is surrounded by all four nitrogen atoms of the Schiff base and six oxygen atoms belonging to three bidentate chelating nitrato ligands. (c) 2006 Elsevier B.V. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1016/j.inoche.2005.12.018-
heal.identifier.secondary<Go to ISI>://000236430700023-
heal.identifier.secondaryhttp://ac.els-cdn.com/S1387700306000074/1-s2.0-S1387700306000074-main.pdf?_tid=03f2ff6ab3639ee9b81e1f6381368775&acdnat=1333036026_3a4ff7a8365d527f3178508b179ce349-
heal.journalNameInorganic Chemistry Communicationsen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2006-
heal.publisherElsevieren
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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