Sulfur-containing dihydro-pyrrolo [60]fullerene derivatives via 1,3-dipolar cycloadditions of glycine imine esters to C-60

dc.contributor.authorIoannou, E.en
dc.contributor.authorHirsch, A.en
dc.contributor.authorElemes, Y.en
dc.date.accessioned2015-11-24T16:48:46Z
dc.date.available2015-11-24T16:48:46Z
dc.identifier.issn0040-4020-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9363
dc.rightsDefault Licence-
dc.subjectfullerenesen
dc.subjectazomethine ylidesen
dc.subject1,3-dipolar cycloadditionsen
dc.subjectdihydro-pyrroleen
dc.subjectsulfidesen
dc.subjectdiels-alder reactionen
dc.subjectamino-acid derivativesen
dc.subjectfullerene derivativesen
dc.subjecthiv-1 proteaseen
dc.subjectpyrimidone derivativesen
dc.subjectchemistryen
dc.subject<60>fullereneen
dc.subjectinhibitorsen
dc.subjectpeptidesen
dc.subjectsultinesen
dc.titleSulfur-containing dihydro-pyrrolo [60]fullerene derivatives via 1,3-dipolar cycloadditions of glycine imine esters to C-60en
heal.abstractC-60 reacts thermally with 1,3-dipoles, formed in situ, from sulfide-bearing imines of glycine esters, and affords dihydro-pyrrolo [60] fullerene derivatives containing a vinylic sulfide group, which were isolated in good yields, and characterized with H-1 and C-13 NMR, FTIR, UV-vis spectroscopies, and with FAB, ESI mass spectrometries. The new derivatives contain a sulfide, an imine, and an ester functionality for further chemical transformations. Mechanistic considerations with regard to the loss of a mercaptan molecule in the course of the cycloaddition are deployed. (C) 2007 Elsevier Ltd. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1016/j.tet.2007.05.011-
heal.identifier.secondary<Go to ISI>://000252082100013-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0040402007008411/1-s2.0-S0040402007008411-main.pdf?_tid=3c631f36-356e-11e3-bdbc-00000aacb35e&acdnat=1381823512_d9ea54897365c1a6f0581c0f7b922ea8-
heal.journalNameTetrahedronen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2007-
heal.publisherElsevieren
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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