Synthesis and Characterization of Neutral Tris(Bidentate) Vanadium(V) Complexes Containing N3s23- and Catecholate Ligands
| dc.contributor.author | Kabanos, T. A. | en |
| dc.contributor.author | Woollins, J. D. | en |
| dc.date.accessioned | 2015-11-24T16:48:56Z | |
| dc.date.available | 2015-11-24T16:48:56Z | |
| dc.identifier.issn | 0300-9246 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9398 | |
| dc.rights | Default Licence | - |
| dc.subject | sulfur-nitrogen ligands | en |
| dc.subject | transition-metal complexes | en |
| dc.subject | crystal-structure | en |
| dc.subject | spectrum | en |
| dc.title | Synthesis and Characterization of Neutral Tris(Bidentate) Vanadium(V) Complexes Containing N3s23- and Catecholate Ligands | en |
| heal.abstract | The preparation and characterisation of complexes of the type [V(N3S2)Cl2L] (L = 2,2'-bipyridyl, 1; or 1,10-phenanthroline, 2) and [V(N3S2)L(L')] [L' = catecholate (cat) or 3,5-di-tert-butylcatecholate (dtbc)] 3-6 is described. The new complexes have been characterised by microanalyses, V-51 NMR, IR and visible spectroscopy as well as electrochemistry. All the new complexes are air stable as solids. Complexes 3 and 4 have a one-electron reversible couple and an anodic peak, whereas the dtbc complexes 5 and 6 have two one-electron reversible redox couples. The V-51 NMR spectra of 1-6 are characteristic, in particular there is a large downfield shift on replacing cat by dtbc. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.secondary | <Go to ISI>://A1991FM50400030 | - |
| heal.journalName | Journal of the Chemical Society-Dalton Transactions | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 1991 | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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