Generation of Core/Shell iron oxide magnetic nanoparticles with polystyrene brushes by atom transfer radical polymerization

dc.contributor.authorGarcia, I.en
dc.contributor.authorTercjak, A.en
dc.contributor.authorZafeiropoulos, N. E.en
dc.contributor.authorStamm, M.en
dc.contributor.authorMondragon, I.en
dc.date.accessioned2015-11-24T17:34:35Z
dc.date.available2015-11-24T17:34:35Z
dc.identifier.issn0887-624X-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/13997
dc.rightsDefault Licence-
dc.subjectatom transfer radical polymerization (atrp)en
dc.subjectatomic force microscopyen
dc.subject(afm)en
dc.subjectft-iren
dc.subjectgraft polymerizationen
dc.subjectmagnetic nanoparticlesen
dc.subjectterminator multifunctional initiatoren
dc.subjectchain transfer polymerizationen
dc.subjectmethyl-methacrylateen
dc.subjectdendritic macromoleculesen
dc.subjectfunctional initiatorsen
dc.subjectsilica nanoparticlesen
dc.subjectdivergent synthesisen
dc.subjectgold nanoparticlesen
dc.subjectiterative strategyen
dc.subjecthybrid materialsen
dc.titleGeneration of Core/Shell iron oxide magnetic nanoparticles with polystyrene brushes by atom transfer radical polymerizationen
heal.abstractThe functionalization of nanoparticle surfaces is required to improve the dispersion of an inorganic material inside an organic matrix. In this work, polystyrene (PS) brushes were grown on the surface of iron oxide magnetic nanoparticles with atom transfer radical polymerization and a grafting-from approach. After polymerization, the magnetic nanoparticles had a graft density of 0.9 PS chains/nm(2). A sacrificial initiator was used to obtain a satisfactory result for the control of the polymerization, as its addition had to generate a sufficient concentration of persistent radicals (deactivator). A variety of techniques, such as Fourier transform infrared spectroscopy, thermogravimetric analysis, gel permeation chromatography, water contact-angle measurements, and atomic force microscopy, were used to characterize the nanoparticles. (c) 2007 Wiley Periodicals, Inc.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDoi 10.1002/Pola.22233-
heal.identifier.secondary<Go to ISI>://000250240300021-
heal.journalNameJournal of Polymer Science Part a-Polymer Chemistryen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2007-
heal.publisherWileyen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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