Aqueous corrosion behaviour of Fe-Ni-B metal glasses

dc.contributor.authorLekatou, A.en
dc.contributor.authorMarinou, A.en
dc.contributor.authorPatsalas, P.en
dc.contributor.authorKarakassides, M. A.en
dc.date.accessioned2015-11-24T17:32:09Z
dc.date.available2015-11-24T17:32:09Z
dc.identifier.issn0925-8388-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/13678
dc.rightsDefault Licence-
dc.subjectmetallic glassesen
dc.subjectcorrosionen
dc.subjectpassivityen
dc.subjectraman spectroscopyen
dc.subjectelectrochemical testingen
dc.subjectelectrochemical-behavioren
dc.subjectnickel-hydroxideen
dc.subjectamorphous-alloysen
dc.subjectpassive layersen
dc.subjectramanen
dc.subjectironen
dc.subjectb2o3en
dc.subjectnaohen
dc.subjectxpsen
dc.titleAqueous corrosion behaviour of Fe-Ni-B metal glassesen
heal.abstractThe corrosion performance of Fe-40Ni-20B (at%) amorphous ribbons in 7N NaOH and 3.5% NaCl, at 25 degrees C, is investigated by potentiodynamic polarization, chronoamperometry and Raman spectroscopy. Immersion in 7N NaOH induces a multiple stage passivation/pseudopassivation, which is associated with the successive formation of (Ni,Fe) compounds based on Fe(3)O(4), Ni(OH)(2)/NiO, FeOOH/Fe(2)O(3), Ni(OH)(2)center dot 2NiOOH and beta NiOOH, Fe(3)O(4), NiO, Fe(2)O(3) and beta NiOOH are responsible for true passivity. Although carbonate ions from the environment have penetrated the passive film, the glass is not susceptible to pitting in 7N NaOH. Despite amorphicity, the glass behaviour in 7N NaOH is governed by the behaviour of its crystalline metallic constituents. The alloy exhibits a slight susceptibility to localized corrosion, in 3.5% NaCl. (C) 2008 Elsevier B.V. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1016/j.jallcom.2008.07.217-
heal.identifier.secondary<Go to ISI>://000270619600124-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0925838808019543/1-s2.0-S0925838808019543-main.pdf?_tid=2b84f28624104e8b7758215bfb57a614&acdnat=1339492613_acaaf0599bad4adcf348973c67416a39-
heal.journalNameJournal of Alloys and Compoundsen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2009-
heal.publisherElsevieren
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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