Preparation and infrared study of magnesium borate gels with a wide composition range

dc.contributor.authorKarakassides, M. A.en
dc.contributor.authorPetridis, D.en
dc.contributor.authorMousdis, G.en
dc.contributor.authorTrapalis, C.en
dc.contributor.authorKordas, G.en
dc.date.accessioned2015-11-24T17:37:33Z
dc.date.available2015-11-24T17:37:33Z
dc.identifier.issn0022-3093-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/14370
dc.rightsDefault Licence-
dc.subjectglassesen
dc.titlePreparation and infrared study of magnesium borate gels with a wide composition rangeen
heal.abstractGels in the system xMgO.(1-x)B2O3 (0.42 less than or equal to x less than or equal to 0.80) have been prepared by hydrolytic polycondensation of boron-butoxide with magnesium methoxide in alcoholic medium. The gels were heated at 400 degrees C in order to obtain organic-free amorphous materials. The infrared spectra of these gels reveal the progressive modification of the borate network with increasing magnesium percentage. The X-ray diffraction patterns of the gels show that calcination at temperatures higher than 400 degrees C leads to crystallization of the amorphous network. For the very high magnesium content glass (x = 0.80), evidence for magnesium carbonate formation is detected.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.secondary<Go to ISI>://A1996VE40600025-
heal.journalNameJournal of Non-Crystalline Solidsen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate1996-
heal.publisherElsevieren
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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