The influence of defects on the electron-transfer and magnetic properties of RbxMn[Fe(CN)(6)](y)center dot zH(2)O

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dc.contributor.authorVertelman, E. J. M.en
dc.contributor.authorMaccallini, E.en
dc.contributor.authorGournis, D.en
dc.contributor.authorRudolf, P.en
dc.contributor.authorBakas, T.en
dc.contributor.authorLuzon, J.en
dc.contributor.authorBroer, R.en
dc.contributor.authorPugzlys, A.en
dc.contributor.authorLummen, T. T. A.en
dc.contributor.authorvan Loosdrecht, P. H. M.en
dc.contributor.authorvan Koningsbruggen, P. J.en
dc.date.accessioned2015-11-24T17:31:11Z
dc.date.available2015-11-24T17:31:11Z
dc.identifier.issn0897-4756-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/13558
dc.rightsDefault Licence-
dc.subjectprussian-blue analogsen
dc.subjectx-ray photoelectronen
dc.subjectrubidium manganese hexacyanoferrateen
dc.subjectphotoinduced ferrimagnetic systemsen
dc.subjectinduced spin changeen
dc.subjectvalence tautomeric transitionen
dc.subjectthermal hysteresis loopen
dc.subjectcobalt-iron cyanideen
dc.subjectphase-transitionen
dc.subjectcharge-transferen
dc.titleThe influence of defects on the electron-transfer and magnetic properties of RbxMn[Fe(CN)(6)](y)center dot zH(2)Oen
heal.abstractThe synthesis and detailed characterization of a few samples of the compound RbxMn[Fe(CN)(6)](y)center dot zH(2)O are described. The composition of the materials significantly depends on the applied preparative conditions. Analysis of spectroscopic results (FTIR, Raman, Fe-57 Mossbauer, XPS) and X-ray powder-diffraction data yielded a further assessment of the difference in structural features in terms of the amount of Fe(CN)6 vacancies and the associated number of water molecules. The characteristic individual magnetic behavior, as well as the metal-to-metal charge-transfer capabilities of the various samples, could be related to significant changes within the structures that appear to be associated with the synthetic method used.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDoi 10.1021/Cm052521x-
heal.identifier.secondary<Go to ISI>://000236499300033-
heal.journalNameChemistry of Materialsen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2006-
heal.publisherAmerican Chemical Societyen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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