Zinc(II) and Nickel(II) Benzoate Complexes from the Use of 1-methyl-4,5-diphenylimidazole
| dc.contributor.author | Kounavi, K. A. | en |
| dc.contributor.author | Manos, M. J. | en |
| dc.contributor.author | Tasiopoulos, A. J. | en |
| dc.contributor.author | Perlepes, S. P. | en |
| dc.contributor.author | Nastopoulos, V. | en |
| dc.date.accessioned | 2015-11-24T16:52:22Z | |
| dc.date.available | 2015-11-24T16:52:22Z | |
| dc.identifier.issn | 1565-3633 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9873 | |
| dc.rights | Default Licence | - |
| dc.subject | hydrogen-bond | en |
| dc.subject | supramolecular chemistry | en |
| dc.subject | crystal-structure | en |
| dc.subject | copper(ii) | en |
| dc.title | Zinc(II) and Nickel(II) Benzoate Complexes from the Use of 1-methyl-4,5-diphenylimidazole | en |
| heal.abstract | Two new complexes, [Zn(O(2)CPh)(2)(L)(2)] center dot 2MeOH (1 center dot 2MeOH) and [Ni(2)(O(2)CPh))(4)(L)(2)] center dot 2MeCN (2 center dot 2MeCN), have been synthesized and characterized by X-ray analysis in the course of an ongoing investigation of the M(II)/X(-)/L [M(II) = Co, Ni, Cu, Zn; X(-) = Cl(-), Br(-), I(-), NCS(-), NO(3)(-), N(3)(-), PhCO(2)(-); L = 1-methyl-4,5-diphenylimidazole] reaction system, aiming at understanding and assessing the relative strength and the way in which the intermolecular interactions control the supramolecular organization of these compounds. In the mononuclear complex 1 center dot 2MeOH, the benzoate ion acts as a monodentate ligand resulting in a distorted tetrahedral N(2)O(2) coordination environment. Complex 2 center dot 2MeCN exhibits a dinuclear paddle-wheel structure; each Ni(II) has a square pyramidal NiNO(4) chromophore with four benzoate oxygens in the basal plane and the pyridine-type nitrogen atom of one ligand L at the apex. The structure of 1 center dot 2MeOH is stabilized by intramolecular pi-pi interactions between aromatic rings of adjacent 4,5-diphenylimidazole moieties; it is a feature also evidenced in similar compounds of the type [MX(2)L(2)]. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | Doi 10.1155/2010/178034 | - |
| heal.identifier.secondary | <Go to ISI>://000281258600001 | - |
| heal.identifier.secondary | http://downloads.hindawi.com/journals/bca/2010/178034.pdf | - |
| heal.journalName | Bioinorg Chem Appl | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2010 | - |
| heal.publisher | Hindawi Publishing Corporation | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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