An Inverse Gas-Chromatographic Study of Compatibility of Food Grade Pvdc Copolymer and Low Volatility Plasticizers
dc.contributor.author | Demertzis, P. G. | en |
dc.contributor.author | Riganakos, K. A. | en |
dc.contributor.author | Akrida-Demertzi, K. | en |
dc.date.accessioned | 2015-11-24T16:48:47Z | |
dc.date.available | 2015-11-24T16:48:47Z | |
dc.identifier.issn | 0959-8103 | - |
dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9366 | |
dc.rights | Default Licence | - |
dc.subject | compatibility | en |
dc.subject | inverse gas chromatography | en |
dc.subject | plasticizers | en |
dc.subject | interaction parameters | en |
dc.subject | poly(methyl methacrylate) | en |
dc.subject | blends | en |
dc.subject | thermodynamics | en |
dc.subject | polymers | en |
dc.subject | systems | en |
dc.subject | pvc | en |
dc.title | An Inverse Gas-Chromatographic Study of Compatibility of Food Grade Pvdc Copolymer and Low Volatility Plasticizers | en |
heal.abstract | The compatibilities of the systems poly(vinylidene chloride-vinyl chloride 80:20)/polyadipate ester and poly(vinylidene chloride-vinyl chloride 80:20)/tri-iso-nonyl trimellitate have been studied in the range 90-110-degrees-C using inverse gas chromatography (IGC). The retention behaviour of the polymer/plasticizer mixtures covering the entire composition range for each component was characterized for 10 probes of different chemical nature. In agreement with previous work, the IGC-derived interaction parameters (X23+) showed an apparent dependence on the chemical nature of the probe, blend composition and temperature. The results predict good polymer/plasticizer compatibility up to c. 0.40 weight fraction of plasticizer for poly(vinylidene chloride-vinyl chloride 80:20)/polyadipate ester blends and to c. 0.50 for poly(vinylidene chloride-vinyl chloride 80:20)/tri-iso-nonyl trimellitate blends. | en |
heal.access | campus | - |
heal.fullTextAvailability | TRUE | - |
heal.identifier.primary | DOI 10.1002/pi.4990250406 | - |
heal.identifier.secondary | <Go to ISI>://A1991GF01700005 | - |
heal.identifier.secondary | http://onlinelibrary.wiley.com/store/10.1002/pi.4990250406/asset/4990250406_ftp.pdf?v=1&t=hmx47cft&s=f19d7f2834cb36502d690109c968a79c654547b7 | - |
heal.journalName | Polymer International | en |
heal.journalType | peer reviewed | - |
heal.language | en | - |
heal.publicationDate | 1991 | - |
heal.publisher | Wiley-Blackwell | en |
heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
heal.type | journalArticle | - |
heal.type.el | Άρθρο Περιοδικού | el |
heal.type.en | Journal article | en |
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