A facile diastereoselective synthesis of functionalized 1,2,3-trisubstituted benzocyclopentenes through the cycloaddition of bis(phenylsulfonyl)iodonium ylides to cyclic alkenes
| dc.contributor.author | Adam, W. | en |
| dc.contributor.author | Gogonas, E. P. | en |
| dc.contributor.author | Hadjiarapoglou, L. P. | en |
| dc.date.accessioned | 2015-11-24T16:54:45Z | |
| dc.date.available | 2015-11-24T16:54:45Z | |
| dc.identifier.issn | 0022-3263 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/10190 | |
| dc.rights | Default Licence | - |
| dc.subject | alkyl sulfones | en |
| dc.subject | rearrangement | en |
| dc.subject | photochemistry | en |
| dc.subject | indanes | en |
| dc.title | A facile diastereoselective synthesis of functionalized 1,2,3-trisubstituted benzocyclopentenes through the cycloaddition of bis(phenylsulfonyl)iodonium ylides to cyclic alkenes | en |
| heal.abstract | The thermal cycloaddition of beta-disulfonyl iodonium ylides to cyclic alkenes affords exclusively 1,2,3-trisubstituted cis(1,2)/cis(2,3)-configured benzocyclopentenes by an electrophilic attack of the ylide on the olefinic double bond. This unsual transformation provides a convenient and direct method for the diastereoselective synthesis of functionalized bicyclo[3.3.0] octanes (characteristic structural units contained in polyquinane natural products), when cyclopentenes are used as cycloalkene partner. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | Doi 10.1021/Jo035362e | - |
| heal.identifier.secondary | <Go to ISI>://000186489000063 | - |
| heal.identifier.secondary | http://pubs.acs.org/doi/pdfplus/10.1021/jo035362e | - |
| heal.journalName | Journal of Organic Chemistry | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2003 | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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