Synthesis, characterization and crystal structure of catena-bis(1,10-phenanthroline)-mu-chloranilatocadmium(Il): a zig-zag polymer based on eight-coordinated square antiprismatic units
| dc.contributor.author | Michaelides, A. | en |
| dc.contributor.author | Papadimitriou, C. D. | en |
| dc.contributor.author | Plakatouras, J. C. | en |
| dc.contributor.author | Skoulika, S. | en |
| dc.contributor.author | Veltsistas, P. G. | en |
| dc.date.accessioned | 2015-11-24T16:49:27Z | |
| dc.date.available | 2015-11-24T16:49:27Z | |
| dc.identifier.issn | 0277-5387 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9487 | |
| dc.rights | Default Licence | - |
| dc.subject | cadmium(ii) | en |
| dc.subject | chloranilate anions | en |
| dc.subject | phenanthroline | en |
| dc.subject | square antiprism | en |
| dc.subject | crystal structures | en |
| dc.subject | chain polymers | en |
| dc.subject | x-ray | en |
| dc.subject | magnetic-properties | en |
| dc.subject | coordination polymers | en |
| dc.subject | chloranilate anion | en |
| dc.subject | complexes | en |
| dc.subject | chain | en |
| dc.subject | 2,5-dihydroxy-1,4-benzoquinone | en |
| dc.subject | electrode | en |
| dc.subject | oxalates | en |
| dc.subject | channels | en |
| dc.title | Synthesis, characterization and crystal structure of catena-bis(1,10-phenanthroline)-mu-chloranilatocadmium(Il): a zig-zag polymer based on eight-coordinated square antiprismatic units | en |
| heal.abstract | [Cd(phen)(2)(CA)](n) (I, where phen is 1,10-phenanthroline and CA(2-) is the dianion of 3,6-dichloro-2,5-dihydroxy-1,4-benzoquinone) has been synthesized and its crystal structure has been determined by single-crystal X-ray diffraction at room temperature. The crystal of I is built from infinite chains of chloranilate-bridged cadmium(II) leading to a zig-zag structure, with the phenanthroline ligands being stacked between the chains. These interactions assist the formation of a closely packed 3D structure. The coordination environment of cadmium(II) - very scarce in its chemistry - is square antiprismatic. The polymer was also characterized with spectroscopic (IR, Raman, DRS) and thermogravimetric (TG, DTA) techniques. (C) 2004 Elsevier Ltd. All rights reserved. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | DOI 10.1016/j.poly.2004.09.013 | - |
| heal.identifier.secondary | <Go to ISI>://000225118900016 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S0277538704003808/1-s2.0-S0277538704003808-main.pdf?_tid=e419e12b4af890e8ec512cc4bf8312ba&acdnat=1333040533_100ec9edf2c84bfb0fea0c326222f57b | - |
| heal.journalName | Polyhedron | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2004 | - |
| heal.publisher | Elsevier | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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