Structures and spectral properties of palladium(II) complexes of 2-acetylpyridine N(4)-dimethylthiosemicarbazone

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dc.contributor.authorKovalaDemertzi, D.en
dc.contributor.authorDomopoulou, A.en
dc.contributor.authorDemertzis, M. A.en
dc.contributor.authorValdesMartinez, J.en
dc.contributor.authorHernandezOrtega, S.en
dc.contributor.authorEspinosaPerez, G.en
dc.contributor.authorWest, D. X.en
dc.contributor.authorSalberg, M. M.en
dc.contributor.authorBain, G. A.en
dc.contributor.authorBloom, P. D.en
dc.date.accessioned2015-11-24T16:48:25Z
dc.date.available2015-11-24T16:48:25Z
dc.identifier.issn0277-5387-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9317
dc.rightsDefault Licence-
dc.subjectmetal ion complexesen
dc.subjectcopper(ii) complexesen
dc.subjectantifungal propertiesen
dc.subjectbiological propertiesen
dc.subjectnickel(ii) complexesen
dc.subjectthiosemicarbazonesen
dc.subjectn-4-dipropylthiosemicarbazonesen
dc.subjectn-4-diethylthiosemicarbazonesen
dc.subjectelectrochemistryen
dc.titleStructures and spectral properties of palladium(II) complexes of 2-acetylpyridine N(4)-dimethylthiosemicarbazoneen
heal.abstractAnions [loss of N(3) hydrogen of 2-acetylpyridine N(4)-dimethylthiosemicarbazone (HAc4DM)] coordinate in a planar conformation to a central palladium(II) through the pyridyl nitrogen, azomethine nitrogen and thiolato sulfur atoms. The fourth coordination site is occupied by either a bromo, chloro or a second Ac4DM ligand bonding via its thiolato sulfur atom. A crystal structure of [Pd(Ac4DM)Br] shows it to be planar, while the structure of [Pd(Ac4DM)(2)] has the unusual coordination of the two anions bonding differently to the palladium centre. Spectral and structural similarities and differences between these and related nickel(II) and copper(II) complexes are considered. Copyright (C) 1996 Elsevier Science Ltden
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.secondary<Go to ISI>://A1996UN04800011-
heal.identifier.secondaryhttp://ac.els-cdn.com/0277538795005382/1-s2.0-0277538795005382-main.pdf?_tid=49c05b22cdfc9512dc9443116744d5af&acdnat=1333028728_6d81d3ee86a5d4cedcdde055eec5bdf0-
heal.journalNamePolyhedronen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate1996-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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