Organotin(IV) complexes with 2-(2 '-pyridyl)quinoxaline (L) - The crystal structure of the [SnEt2Cl2L]center dot 0.5 benzene

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dc.contributor.authorGaroufis, A.en
dc.contributor.authorKoutsodimou, A.en
dc.contributor.authorRaptopoulou, C. P.en
dc.contributor.authorSimopoulos, A.en
dc.contributor.authorKatsaros, N.en
dc.date.accessioned2015-11-24T16:43:36Z
dc.date.available2015-11-24T16:43:36Z
dc.identifier.issn0277-5387-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8720
dc.rightsDefault Licence-
dc.subjectdiorganotin(iv) complexesen
dc.subject2-(2 '-pyridyl)quinoxalineen
dc.subjectantitumoren
dc.subjectcrystal structureen
dc.subjectstate c-13 nmren
dc.subjectbiheteroaromatic ligand 2-(2'-pyridyl)quinoxalineen
dc.subjectsn-me angleen
dc.subjectmethyltin(iv) compoundsen
dc.subjectdiorganotin dihalideen
dc.subjectantitumour activityen
dc.subjectmolecular-structureen
dc.subjectmetal-complexesen
dc.subjecttin(iv)en
dc.subjectderivativesen
dc.titleOrganotin(IV) complexes with 2-(2 '-pyridyl)quinoxaline (L) - The crystal structure of the [SnEt2Cl2L]center dot 0.5 benzeneen
heal.abstractComplexes of 2-(2'-pyridyl)quinoxaline (L) with R2SnCl2 (R=Me, Et, Bu-n) have been synthesized and characterized using IR, far-IR, Sn-119 Mossbauer,H-1 and C-13 spectroscopies. The X-ray crystal structure of Et2SnCl2L shows a bidentate chelating behaviour of L, which is observed in all the diorganotin compounds presented. Interaction of the ligand L with SnCl4 resulted in the formation of a salt with the formula [(LH)(2)](2+)[SnCl6](2-). Solution studies of the complexes R2SnCl2L (R=Me, Et, Bu-n) revealed partial dissociation of the ligand in chloroform. (C) 1999 Elsevier Science Ltd. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDoi 10.1016/S0277-5387(99)00217-X-
heal.identifier.secondary<Go to ISI>://000083653000008-
heal.identifier.secondaryhttp://ac.els-cdn.com/S027753879900217X/1-s2.0-S027753879900217X-main.pdf?_tid=694e78c0-5809-11e3-ac51-00000aacb361&acdnat=1385628499_2cde6da526f54a502710b27d28147631-
heal.journalNamePolyhedronen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate1999-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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