Suzuki-Miyaura cross-coupling reaction of aryl bromides and chlorides with phenylboronic acid under aerobic conditions catalyzed by palladium complexes with thiosemicarbazone ligands

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dc.contributor.authorKostas, I. D.en
dc.contributor.authorAndreadaki, F. J.en
dc.contributor.authorKovala-Demertzi, D.en
dc.contributor.authorPrentjas, C.en
dc.contributor.authorDemertzis, M. A.en
dc.date.accessioned2015-11-24T16:48:50Z
dc.date.available2015-11-24T16:48:50Z
dc.identifier.issn0040-4039-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9376
dc.rightsDefault Licence-
dc.subjectthiosemicarbazoneen
dc.subjectphosphine-free liganden
dc.subjectpalladium complexen
dc.subjectsuzuki-miyaura cross-couplingen
dc.subjectc-c bond formationen
dc.subjecthomogeneous catalysisen
dc.subjectbond-forming reactionsen
dc.subjectheck reactionen
dc.subjectorganoboron compoundsen
dc.subjectrecyclable catalystsen
dc.subjectcrystal-structureen
dc.subjectc-cen
dc.subjectcoordinationen
dc.subjectprecursoren
dc.subjecthalidesen
dc.subjectrhodiumen
dc.titleSuzuki-Miyaura cross-coupling reaction of aryl bromides and chlorides with phenylboronic acid under aerobic conditions catalyzed by palladium complexes with thiosemicarbazone ligandsen
heal.abstractFor the first time, palladium complexes with salicylaldehyde thiosemicarbazones were applied as catalyst precursors to the Suzuki-Miyaura reaction. These air and moisture stable phosphine-free systems efficiently catalyze the cross-coupling of aryl bromides and chlorides (from electron rich to electron poor) with phenylboronic acid in DMF/H2O at 100 degrees C for 24 h, using Na2CO3 as base, without addition of free ligand or any promoting additive, and under aerobic conditions no significant homocoupling of phenylboronic acid to unsubstituted biphenyl was observed. (C) 2005 Elsevier Ltd. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1016/j.tetlet.2005.02.003-
heal.identifier.secondary<Go to ISI>://000227506100002-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0040403905002637/1-s2.0-S0040403905002637-main.pdf?_tid=f5a44252cf6ad83c57acba27af6b7ec5&acdnat=1333028622_3d42dc71f7009e25e95d2edb653f0acb-
heal.journalNameTetrahedron Letten
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2005-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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