Effect of 1-phenyl-2,4-dithiobiuret as secondary accelerator on cure characteristics and vulcanisate properties of natural rubber-styrene/butadiene rubber blends

dc.contributor.authorAprem, A. S.en
dc.contributor.authorJoseph, K.en
dc.contributor.authorThomas, S.en
dc.contributor.authorBarkoula, N. M.en
dc.contributor.authorKarger-Kocsis, J.en
dc.date.accessioned2015-11-24T17:33:21Z
dc.date.available2015-11-24T17:33:21Z
dc.identifier.issn1465-8011-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/13851
dc.rightsDefault Licence-
dc.titleEffect of 1-phenyl-2,4-dithiobiuret as secondary accelerator on cure characteristics and vulcanisate properties of natural rubber-styrene/butadiene rubber blendsen
heal.abstractBlends of natural rubber and styrene/butadiene rubber have been cured using a new binary accelerator system containing 1-phenyl-2,4-ditliobiuret (DTB). This new accelerator was synthesised and used in combination with sulphenamides such as dicyclohexyl benzothiazyl sulphenamide, tertiary butyl benzothiazole sulphenamide and morpholinothio benzothiazole sulphenamide. A significant reduction in cure time was observed with the addition of DTB. Network characterisation of the vulcanisates was carried out by the estimation of crosslink density and relative proportions of crosslinks. The mechanical properties of the vulcanisates improved upon addition of DTB. Dynamic mechanical analysis was carried out to study the effect of the new accelerator on entanglement density and modulus. Based on the processing behaviour, mechanical properties and chemical characterisation it was found that DTB could be effectively used as a secondary accelerator in the curing of NR-SBR blends. (C) 2003 IoM Communications Ltd.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDoi 10.1179/146580103225009130-
heal.identifier.secondary<Go to ISI>://000182124500001-
heal.journalNamePlastics Rubber and Compositesen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2003-
heal.publisherManey Publishingen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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