A flexible Cd2+ metal organic framework with a unique (3,3,6)-connected topology, unprecedented secondary building units and single crystal to single crystal solvent exchange properties
| dc.contributor.author | Kyprianidou, E. J. | en |
| dc.contributor.author | Papaefstathiou, G. S. | en |
| dc.contributor.author | Manos, M. J. | en |
| dc.contributor.author | Tasiopoulos, A. J. | en |
| dc.date.accessioned | 2015-11-24T16:54:55Z | |
| dc.date.available | 2015-11-24T16:54:55Z | |
| dc.identifier.issn | 1466-8033 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/10223 | |
| dc.rights | Default Licence | - |
| dc.subject | imidazolate frameworks | en |
| dc.subject | sorption properties | en |
| dc.subject | chemistry | en |
| dc.subject | storage | en |
| dc.subject | family | en |
| dc.subject | ligand | en |
| dc.subject | state | en |
| dc.title | A flexible Cd2+ metal organic framework with a unique (3,3,6)-connected topology, unprecedented secondary building units and single crystal to single crystal solvent exchange properties | en |
| heal.abstract | A new flexible Cd2+ metal organic framework (MOF), denoted as UCY-3, which is the second example of a MOF with the ligand H3CIP [H3CIP = 5-(4-carboxybenzylideneamino)isophthalic acid], is reported. It shows a unique (3,3,6)-connected topology and is based on a neutral non-oxo triangular [Cd-3(COO)(6)] secondary building unit that appears for the first time in MOFs chemistry. UCY-3 displays significant structural flexibility, capability for exchange of the guest solvents by various organic molecules in a single-crystal-to-single-crystal fashion as well as breathing capacity allowing the incorporation of relatively large amount of benzene into its pores. Overall this work indicates that MOFs based on semi-rigid polytopic ligands may adopt unprecedented structural types and exhibit unexpectedly high absorption capacities for relatively bulky organic molecules, as a result of their flexibility and breathing capability. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | Doi 10.1039/C2ce25913c | - |
| heal.identifier.secondary | <Go to ISI>://000311969400013 | - |
| heal.identifier.secondary | http://pubs.rsc.org/en/Content/ArticleLanding/2012/CE/c2ce25913c | - |
| heal.journalName | Crystengcomm | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2012 | - |
| heal.publisher | Royal Society of Chemistry | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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