Formation of Chlorinated Hydrocarbons by Water Chlorination
| dc.contributor.author | Lahaniatis, E. S. | en |
| dc.contributor.author | Bergheim, W. | en |
| dc.contributor.author | Kotzias, D. | en |
| dc.contributor.author | Pilidis, G. | en |
| dc.date.accessioned | 2015-11-24T16:35:07Z | |
| dc.date.available | 2015-11-24T16:35:07Z | |
| dc.identifier.issn | 0045-6535 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/7902 | |
| dc.rights | Default Licence | - |
| dc.subject | ozonation | en |
| dc.title | Formation of Chlorinated Hydrocarbons by Water Chlorination | en |
| heal.abstract | Model experiments were carried out on the reaction behaviour of benzene, phenol and phenylalanine during chlorination with NaOCl in aqueous solution. The influence of the pH-value, concentration, reaction time and UV-light were also determined. These experiments were conducted under conditions similar to chlorination of water and the reaction products were identified by capillary GC and GC/MS. All chlorinated isomers of benzene including HCB, formed by chlorination of benzene, were identified and quantified. However, monochlorobenzene was the major reaction product (in mu g/l-concentrations). The chlorinated organic substances formed by the reaction of phenol with NaOCl were determined quantitatively. Phenylalanine/NaOCl reaction lead to the formation of 22 chlorinated organic compounds. Thirteen of these were identified and quantified. Under the influence of UV-light, the reaction of benzene/NaOCl formed primarily higher chlorinated propane derivatives, chlorinated phenols and octachlorocyclohexandiene derivatives. Similar results were obtained with the reaction of phenol/NaOCl and the phenylalanine/NaOCl. The formation of chloroform during all these reactions were determined quantitatively. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.secondary | <Go to ISI>://A1994MV45100002 | - |
| heal.journalName | Chemosphere | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 1994 | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιών | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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