Study of the geometric preferences of copper(I) halid coordnation compounds with triarylphosphines. Crystal structures of [CuBr{P(o-tolyl)3}]2 and [CuCl{P(otolyl)3}]2
| dc.contributor.author | Hadjikakou, S. K. | en |
| dc.contributor.author | Akrivos, P. D. | en |
| dc.contributor.author | Karagiannidis, P. | en |
| dc.contributor.author | Mentzafos, D. | en |
| dc.contributor.author | Terzis, A. | en |
| dc.date.accessioned | 2015-11-24T16:48:35Z | |
| dc.date.available | 2015-11-24T16:48:35Z | |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9345 | |
| dc.rights | Default Licence | - |
| dc.title | Study of the geometric preferences of copper(I) halid coordnation compounds with triarylphosphines. Crystal structures of [CuBr{P(o-tolyl)3}]2 and [CuCl{P(otolyl)3}]2 | en |
| heal.abstract | The crystal structures of [CuCl(totp)]2 and [CuBr(totp)]2, totp=tri-o-tolylphosphine, are reported. They present planar Cu2X2 cores with trigonal-planar Cu(I) atoms, the Cuξ—ΈP axes bisecting in both cases the Xξ—ΈCuξ—ΈX angles. Crystallographic data: for [CuCl(totp)]2a = 9.1758(7), b = 10.4805(8), c = 20.481(1) Γ…, Ξ² = 99.279(2)Β°, with Z = 2 and space group P21/n; for [CuBr(totp)]2a = 9.215(1), b = 10.203(1), c = 11.275(1) Γ…, Ξ± = 78.422(5), Ξ² = 100.691(5), Ξ³ = 80.789(4)Β°, with Z = 1 and space group PView the MathML source. The slight geometric changes observed between the two compounds, especially the more acute Xξ—ΈCuξ—ΈX angle in the case of [CuCl(totp)]2 are investigated with Extended HΓΌckel calculations on model compounds. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.secondary | http://www.sciencedirect.com/science/article/pii/S0020169300828194 | - |
| heal.journalName | Inorg.Chim. Acta | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 1993 | - |
| heal.publisher | Elsevier | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
Αρχεία
Φάκελος/Πακέτο αδειών
1 - 1 of 1
Φόρτωση...
- Ονομα:
- license.txt
- Μέγεθος:
- 1.74 KB
- Μορφότυπο:
- Item-specific license agreed upon to submission
- Περιγραφή: