Bis(sulfonyl)methyl insertion into alkenyl versus phenyl carbon-hydrogen bonds in the reaction of bis(sulfonyl)iodonium ylides with highly phenylated ethylenes

dc.contributor.authorAdam, W.en
dc.contributor.authorGogonas, E. P.en
dc.contributor.authorHadjiarapoglou, L. P.en
dc.date.accessioned2015-11-24T16:53:13Z
dc.date.available2015-11-24T16:53:13Z
dc.identifier.issn1434-193X-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9988
dc.rightsDefault Licence-
dc.subjectinsertionsen
dc.subjectrhodiumen
dc.subjectylidesen
dc.subjectcatalyzed intramolecular cyclopropanationsen
dc.subjectpolyvalent iodine compoundsen
dc.subjectiodonium ylidesen
dc.subjectphenyliodonium ylidesen
dc.subjectch-insertionsen
dc.subjectcycloadditionen
dc.subjectdecompositionen
dc.subjectchemistryen
dc.titleBis(sulfonyl)methyl insertion into alkenyl versus phenyl carbon-hydrogen bonds in the reaction of bis(sulfonyl)iodonium ylides with highly phenylated ethylenesen
heal.abstractThe reaction of bis(sulfonyl)iodonium ylides alpha-gamma with triphenylethylene (2a) and tetraphenylethylene (2b) affords insertion products into the alkenyl and phenyl carbon-hydrogen bonds of the substrate. A mechanistically perplexing feature is the diversity displayed in the reactivity pattern of the bis(sulfonyl)iodonium ylides in their reaction with the phenylated alkenes.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.secondary<Go to ISI>://000181724600016-
heal.identifier.secondaryhttps://docs.google.com/file/d/0BxfLht5wJUEIYTEwMDk4N2MtZmQ3My00OWMxLWJlZWMtZjIxYzFjNjRkMTYy/edit?hl=en-
heal.journalNameEuropean Journal of Organic Chemistryen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2003-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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