A complementary study of bonding and electronic structure of amorphous carbon films by electron spectroscopy and optical techniques

dc.contributor.authorPatsalas, P.en
dc.contributor.authorHandrea, M.en
dc.contributor.authorLogothetidis, S.en
dc.contributor.authorGioti, M.en
dc.contributor.authorKennou, S.en
dc.contributor.authorKautek, W.en
dc.date.accessioned2015-11-24T17:30:54Z
dc.date.available2015-11-24T17:30:54Z
dc.identifier.issn0925-9635-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/13528
dc.rightsDefault Licence-
dc.subjectamorphous carbonen
dc.subjectelectron spectroscopyen
dc.subjectellipsometryen
dc.subjectsputteringen
dc.subjectthin-filmsen
dc.subjectdiamond filmsen
dc.subjectsp(3) contenten
dc.subjectxpsen
dc.subjectellipsometryen
dc.subjectgraphiteen
dc.subjectdensityen
dc.titleA complementary study of bonding and electronic structure of amorphous carbon films by electron spectroscopy and optical techniquesen
heal.abstractA complementary study of composition and bonding of sputtered a-C films, deposited on Si(001) substrates with various bias voltages (V-b) applied to the substrate during deposition is presented. The sp(3) and sp(3) fractions in the films were calculated by deconvolution of the X-ray photoelectron spectroscopy (XPS) Cls peak and studied by the differential auger electron spectroscopy (AES) C1s peak signal. The results of this analysis are compared with the estimation of sp(3) fraction calculated by spectroscopic ellipsometry (SE) and validated using density measurements by X-ray reflectivity. It was observed a considerable increase of sp(3) content in films deposited with negative V-b. The respective sp(3) and sp(2) fractions and Ar concentration with respect to the V-b and the depth profile analysis give valuable information on the deposition mechanism of the sputtered a-C films. XPS valence band spectra provided the electron density of states in the a-C films' valence band. The characteristic broad p band of diamond was prominent in most of the films. The valence band structure of the films was correlated with their optical response measured by SE. (C) 2001 Elsevier Science B.V. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDoi 10.1016/S0925-9635(00)00480-5-
heal.identifier.secondary<Go to ISI>://000168730600125-
heal.journalNameDiamond and Related Materialsen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2001-
heal.publisherElsevieren
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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