Self-organization of four symmetric tri-phenyl-benzene derivatives
| dc.contributor.author | Vergadou, V. | en |
| dc.contributor.author | Pistolis, G. | en |
| dc.contributor.author | Michaelides, A. | en |
| dc.contributor.author | Varvounis, G. | en |
| dc.contributor.author | Siskos, M. | en |
| dc.contributor.author | Boukos, N. | en |
| dc.contributor.author | Skoulika, S. | en |
| dc.date.accessioned | 2015-11-24T16:46:53Z | |
| dc.date.available | 2015-11-24T16:46:53Z | |
| dc.identifier.issn | 1528-7483 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9118 | |
| dc.rights | Default Licence | - |
| dc.subject | hydrogen-bonded networks | en |
| dc.subject | crystal-structures | en |
| dc.subject | excimer formation | en |
| dc.subject | trimesic acid | en |
| dc.subject | fluorescence | en |
| dc.subject | complexes | en |
| dc.subject | cellulose | en |
| dc.subject | emission | en |
| dc.subject | phases | en |
| dc.subject | hosts | en |
| dc.title | Self-organization of four symmetric tri-phenyl-benzene derivatives | en |
| heal.abstract | The self-assembly of four symmetrically substituted tri-aryl-benzene derivatives of formula C24H15X3, where X = H (1), Cl (2), COOMe (3), and COOH (4), was studied as a function of the substituent X. Crystal packing analysis of compounds 1-3 showed that in 1, there are no strong face-to-face stacking interactions, whereas in both compounds 2 and 3, molecular columns were formed, held by numerous "lateral" C-H center dot center dot center dot Cl and C-H center dot center dot center dot O hydrogen bonds, respectively. However, strong intermolecular face-to-face aromatic interactions, appropriate for excimer formation, were observed only in 3, in line with results obtained by fluorescence spectroscopy. The pi-pi aromatic interactions are significantly stronger in the case of the triacid 4, but a lack of adequate single crystals of this compound prevented any detailed study for correlating crystal architecture with fluorescence emission observed. However, FT-IR and TEM experiments showed the existence of dimeric H-bonds and short (0.35 nm) distances between the phenyl rings. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | Doi 10.1021/Cg060183m | - |
| heal.identifier.secondary | <Go to ISI>://000241702400015 | - |
| heal.identifier.secondary | http://pubs.acs.org/doi/abs/10.1021/cg060183m | - |
| heal.journalName | Crystal Growth & Design | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2006 | - |
| heal.publisher | American Chemical Society | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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