Self-assembly of dialkyltin(IV) moieties and a thiosemicarbone to a trinuclear macrocycle and the unprecedented formation of two pseudo-polymorphs with different cavities
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Kovala-Demertzi, D.
Wiecek, J.
Plakatouras, J. C.
Ciunik, Z.
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peer reviewed
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Crystengcomm
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The reaction of dimethyltin(IV)oxide with pyruvic acid thiosemicarbazone (H(2)pt) and subsequent recrystallization from THF leads to the formation two pseudo-polymorphs based on triangular [(CH3)(2)Sn(pt)](3) units; one of them [(CH3)(2)Sn(pt)](3).3THF (1) with tubular cavities while the other [(CH3)(2)Sn(pt)](3).1.5THF (2) is a H-bonded 3D network with truncated tetrahedral cavities.
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inorganic 3d networks, crystal-structure, palladium(ii) complexes, antiproliferative activity, platinum(ii) complexes, solid-state, phenylboronic acid, 2-acetyl pyridine, x-ray, ligand
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<Go to ISI>://000259411200003
http://pubs.rsc.org/en/Content/ArticleLanding/2008/CE/b809216h
http://pubs.rsc.org/en/Content/ArticleLanding/2008/CE/b809216h
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en
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Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας