Self-assembly of dialkyltin(IV) moieties and a thiosemicarbone to a trinuclear macrocycle and the unprecedented formation of two pseudo-polymorphs with different cavities

dc.contributor.authorKovala-Demertzi, D.en
dc.contributor.authorWiecek, J.en
dc.contributor.authorPlakatouras, J. C.en
dc.contributor.authorCiunik, Z.en
dc.date.accessioned2015-11-24T16:46:52Z
dc.date.available2015-11-24T16:46:52Z
dc.identifier.issn1466-8033-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9115
dc.rightsDefault Licence-
dc.subjectinorganic 3d networksen
dc.subjectcrystal-structureen
dc.subjectpalladium(ii) complexesen
dc.subjectantiproliferative activityen
dc.subjectplatinum(ii) complexesen
dc.subjectsolid-stateen
dc.subjectphenylboronic aciden
dc.subject2-acetyl pyridineen
dc.subjectx-rayen
dc.subjectliganden
dc.titleSelf-assembly of dialkyltin(IV) moieties and a thiosemicarbone to a trinuclear macrocycle and the unprecedented formation of two pseudo-polymorphs with different cavitiesen
heal.abstractThe reaction of dimethyltin(IV)oxide with pyruvic acid thiosemicarbazone (H(2)pt) and subsequent recrystallization from THF leads to the formation two pseudo-polymorphs based on triangular [(CH3)(2)Sn(pt)](3) units; one of them [(CH3)(2)Sn(pt)](3).3THF (1) with tubular cavities while the other [(CH3)(2)Sn(pt)](3).1.5THF (2) is a H-bonded 3D network with truncated tetrahedral cavities.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDoi 10.1039/B809216h-
heal.identifier.secondary<Go to ISI>://000259411200003-
heal.identifier.secondaryhttp://pubs.rsc.org/en/Content/ArticleLanding/2008/CE/b809216h-
heal.journalNameCrystengcommen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2008-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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