Reaction of C-60 with Dimethyldioxirane - Formation of an Epoxide and a 1,3-Dioxolane Derivative
| dc.contributor.author | Elemes, Y. | en |
| dc.contributor.author | Silverman, S. K. | en |
| dc.contributor.author | Sheu, C. M. | en |
| dc.contributor.author | Kao, M. | en |
| dc.contributor.author | Foote, C. S. | en |
| dc.contributor.author | Alvarez, M. M. | en |
| dc.contributor.author | Whetten, R. L. | en |
| dc.date.accessioned | 2015-11-24T16:46:03Z | |
| dc.date.available | 2015-11-24T16:46:03Z | |
| dc.identifier.issn | 0570-0833 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9023 | |
| dc.rights | Default Licence | - |
| dc.subject | all-carbon molecules | en |
| dc.subject | enol ethers | en |
| dc.subject | c-60 | en |
| dc.subject | esters | en |
| dc.title | Reaction of C-60 with Dimethyldioxirane - Formation of an Epoxide and a 1,3-Dioxolane Derivative | en |
| heal.abstract | Not an oxygen-bridged annulene (structural type 1) but rather an epoxide (structural type 2) is the product of the reaction of dimethyldioxirane with C60. In a competing reaction, a 1,3-dioxolane (structural type 3) is formed-probably by a diradical mechanism. Cleavage of acetone from 3 leading to 2 was not observed at temperatures up to 110-degrees-C. Compound 3 could provide access to ring-opened fullerenes. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | DOI 10.1002/anie.199203511 | - |
| heal.identifier.secondary | <Go to ISI>://A1992HX98600035 | - |
| heal.identifier.secondary | http://onlinelibrary.wiley.com/store/10.1002/anie.199203511/asset/199203511_ftp.pdf?v=1&t=hmstwv7f&s=552b8ca42c739a579e3915cb393db12e1a134eea | - |
| heal.journalName | Angewandte Chemie-International Edition in English | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 1992 | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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