Regioselective Synthesis of [1,2,3]-Triazoles Catalyzed by Cu(I) Generated in situ from Cu(0) Nanosize Activated Powder and Amine Hydrochloride Salts
| dc.contributor.author | Fokas, D. | en |
| dc.contributor.author | Orgueira, H. | en |
| dc.contributor.author | Isome, Y. | en |
| dc.contributor.author | Baldino, C. M. | en |
| dc.contributor.author | Chan, A. S. | en |
| dc.date.accessioned | 2015-11-24T17:37:56Z | |
| dc.date.available | 2015-11-24T17:37:56Z | |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/14420 | |
| dc.rights | Default Licence | - |
| dc.subject | Cu(I) generated in situ | en |
| dc.subject | Triazoles | en |
| dc.subject | Regioselectivesynthesis | en |
| dc.title | Regioselective Synthesis of [1,2,3]-Triazoles Catalyzed by Cu(I) Generated in situ from Cu(0) Nanosize Activated Powder and Amine Hydrochloride Salts | en |
| heal.abstract | A straightforward and efficient method for the regioselectivesynthesis of functionalized 1,4-disubstituted [1,2,3]-triazoles, from terminal alkynes and azides, has been established utilizing Cu(0) as the source of the catalytic species. The presumed catalytic Cu(I) species is generated by the combination of 10 mol % copper nanosizeactivatedpowder and 1 equiv of an aminehydrochloridesalt. The addition of an aminehydrochloridesalt into the reaction mixture enhanced the dissolution of copper metal, and subsequently facilitated the formation of the Cu(I)-acetylide intermediate required for the regioselective cycloaddition. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | http://dx.doi.org/10.1016/j.tetlet.2005.02.127 | - |
| heal.identifier.secondary | http://www.sciencedirect.com/science/article/pii/S0040403905004363 | - |
| heal.journalName | Tetrahedron Lett | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2005 | - |
| heal.publisher | Elsevier | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικών | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
Αρχεία
Φάκελος/Πακέτο αδειών
1 - 1 of 1
Φόρτωση...
- Ονομα:
- license.txt
- Μέγεθος:
- 1.74 KB
- Μορφότυπο:
- Item-specific license agreed upon to submission
- Περιγραφή: