O-17 and H-1-N-15 Heteronuclear Multiple-Quantum Coherence (H-1-N-15 Hmqc) Nmr of Linear Amides - Evidence of an out-of-Plane (Torsion Angle) Deformation of the Amide Bond and Pyramidicity at the Amide Nitrogen
| dc.contributor.author | Gerothanassis, I. P. | en |
| dc.contributor.author | Troganis, A. | en |
| dc.contributor.author | Vakka, C. | en |
| dc.date.accessioned | 2015-11-24T16:42:59Z | |
| dc.date.available | 2015-11-24T16:42:59Z | |
| dc.identifier.issn | 0040-4020 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8631 | |
| dc.rights | Default Licence | - |
| dc.subject | nuclear magnetic-resonance | en |
| dc.subject | chemical-shifts | en |
| dc.subject | spectroscopy | en |
| dc.subject | peptides | en |
| dc.subject | protons | en |
| dc.title | O-17 and H-1-N-15 Heteronuclear Multiple-Quantum Coherence (H-1-N-15 Hmqc) Nmr of Linear Amides - Evidence of an out-of-Plane (Torsion Angle) Deformation of the Amide Bond and Pyramidicity at the Amide Nitrogen | en |
| heal.abstract | O-17 and H-1-N-15 heteronuclear multiple quantum coherence NMR studies of linear amides demonstrate the ready occurence of an out-of-plane (torsion angle) deformation of the amide bond and pyramidicity at the amide nitrogen for the sterically hindered trans-isomer of N-tert-butylformamide. Solvent accessibility, steric hindrance and, thus, torsion angle deformation is shown to be strongly solvent dependent. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | Doi 10.1016/0040-4020(95)00551-I | - |
| heal.identifier.secondary | <Go to ISI>://A1995RP93400017 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/004040209500551I/1-s2.0-004040209500551I-main.pdf?_tid=90f92fb0-3247-11e3-8413-00000aab0f26&acdnat=1381477051_921656a0dc8705454da7979cba6e96d1 | - |
| heal.journalName | Tetrahedron | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 1995 | - |
| heal.publisher | Elsevier | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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