Effect of adsorbent particle size and temperature on water-ethanol separation by starchy and cellulosic substrates
Φόρτωση...
Ημερομηνία
Συγγραφείς
Vareli, G. D.
Demertzis, P. G.
Akrida-Demertzi, K.
Τίτλος Εφημερίδας
Περιοδικό ISSN
Τίτλος τόμου
Εκδότης
Springer Verlag (Germany)
Περίληψη
Τύπος
Είδος δημοσίευσης σε συνέδριο
Είδος περιοδικού
peer reviewed
Είδος εκπαιδευτικού υλικού
Όνομα συνεδρίου
Όνομα περιοδικού
Zeitschrift Fur Lebensmittel-Untersuchung Und-Forschung a-Food Research and Technology
Όνομα βιβλίου
Σειρά βιβλίου
Έκδοση βιβλίου
Συμπληρωματικός/δευτερεύων τίτλος
Περιγραφή
Inverse gas chromatography was used to study the adsorption of water and ethanol on two starchy (cornmeal and wheatflour) and one cellulosic (wheat straw) substrate, in the temperature range 50-90 degrees C, Three particle size fractions of each substrate were investigated -180-250 mu m. 160-180 mu m and 125-160 mu m. denoted, respectively, by: 60-80 mesh, 80-100 mesh and 100-120 mesh. Values for the separation factor and for thermodynamic parameters. such as Gibbs free energy and enthalpy of adsorption. were calculated from the chromatographic retention data. The results showed that water was adsorbed more strongly than ethanol on all substrates, at all temperatures. In addition, it was found that lower temperatures were more favourable for the adsorption of both solutes. There was no significant difference between values of separation capacity of the three fractions of wheat straw. In contrast, the separation capacities of starchy materials with smaller particle sizes, i.e. 80-100 mesh and 100-120 mesh, were greater. The 100-120 mesh wheatflour fraction exhibited the highest separation at all temperatures.
Περιγραφή
Λέξεις-κλειδιά
water, ethanol, separation, adsorbent particle size, inverse gas chromatography, adsorption, biomass, systems, vapors
Θεματική κατηγορία
Παραπομπή
Σύνδεσμος
<Go to ISI>://000075599000007
http://download.springer.com/static/pdf/70/art%253A10.1007%252Fs002170050305.pdf?auth66=1382255276_4ebf7d12a77ffccedd0816987242a03b&ext=.pdf
http://download.springer.com/static/pdf/70/art%253A10.1007%252Fs002170050305.pdf?auth66=1382255276_4ebf7d12a77ffccedd0816987242a03b&ext=.pdf
Γλώσσα
en
Εκδίδον τμήμα/τομέας
Όνομα επιβλέποντος
Εξεταστική επιτροπή
Γενική Περιγραφή / Σχόλια
Ίδρυμα και Σχολή/Τμήμα του υποβάλλοντος
Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας