Effect of adsorbent particle size and temperature on water-ethanol separation by starchy and cellulosic substrates

dc.contributor.authorVareli, G. D.en
dc.contributor.authorDemertzis, P. G.en
dc.contributor.authorAkrida-Demertzi, K.en
dc.date.accessioned2015-11-24T16:56:38Z
dc.date.available2015-11-24T16:56:38Z
dc.identifier.issn1431-4630-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/10465
dc.rightsDefault Licence-
dc.subjectwateren
dc.subjectethanolen
dc.subjectseparationen
dc.subjectadsorbent particle sizeen
dc.subjectinverse gas chromatographyen
dc.subjectadsorptionen
dc.subjectbiomassen
dc.subjectsystemsen
dc.subjectvaporsen
dc.titleEffect of adsorbent particle size and temperature on water-ethanol separation by starchy and cellulosic substratesen
heal.abstractInverse gas chromatography was used to study the adsorption of water and ethanol on two starchy (cornmeal and wheatflour) and one cellulosic (wheat straw) substrate, in the temperature range 50-90 degrees C, Three particle size fractions of each substrate were investigated -180-250 mu m. 160-180 mu m and 125-160 mu m. denoted, respectively, by: 60-80 mesh, 80-100 mesh and 100-120 mesh. Values for the separation factor and for thermodynamic parameters. such as Gibbs free energy and enthalpy of adsorption. were calculated from the chromatographic retention data. The results showed that water was adsorbed more strongly than ethanol on all substrates, at all temperatures. In addition, it was found that lower temperatures were more favourable for the adsorption of both solutes. There was no significant difference between values of separation capacity of the three fractions of wheat straw. In contrast, the separation capacities of starchy materials with smaller particle sizes, i.e. 80-100 mesh and 100-120 mesh, were greater. The 100-120 mesh wheatflour fraction exhibited the highest separation at all temperatures.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1007/s002170050305-
heal.identifier.secondary<Go to ISI>://000075599000007-
heal.identifier.secondaryhttp://download.springer.com/static/pdf/70/art%253A10.1007%252Fs002170050305.pdf?auth66=1382255276_4ebf7d12a77ffccedd0816987242a03b&ext=.pdf-
heal.journalNameZeitschrift Fur Lebensmittel-Untersuchung Und-Forschung a-Food Research and Technologyen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate1998-
heal.publisherSpringer Verlag (Germany)en
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

Αρχεία

Φάκελος/Πακέτο αδειών

Προβολή: 1 - 1 of 1
Φόρτωση...
Μικρογραφία εικόνας
Ονομα:
license.txt
Μέγεθος:
1.74 KB
Μορφότυπο:
Item-specific license agreed upon to submission
Περιγραφή: