Esterification reactions catalyzed by lipases immobilized in organogels: effect of temperature and substrate diffusion

dc.contributor.authorZoumpanioti, M.en
dc.contributor.authorParmaklis, P.en
dc.contributor.authorde Maria, P. D.en
dc.contributor.authorStamatis, H.en
dc.contributor.authorSinisterra, J. V.en
dc.contributor.authorXenakis, A.en
dc.date.accessioned2015-11-24T16:34:08Z
dc.date.available2015-11-24T16:34:08Z
dc.identifier.issn0141-5492-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/7764
dc.rightsDefault Licence-
dc.subjectactivation energyen
dc.subjectcatalysisen
dc.subjectdiffusionen
dc.subjectlipaseen
dc.subjectorganogelsen
dc.subjecttemperatureen
dc.subjectmicroemulsion-based organogelsen
dc.subjectin-oil microemulsionsen
dc.subjectgelsen
dc.subjectkineticsen
dc.titleEsterification reactions catalyzed by lipases immobilized in organogels: effect of temperature and substrate diffusionen
heal.abstractRhizomucor miehei lipase was immobilized in hydroxy(propylmethyl) cellulose or agar gels containing lecithin or AOT microemulsions. The effect of the diffusion of substrates and products to this catalyst was studied, as well as the effect of temperature on the initial rate of ester synthesis. The composition of the gel affects the reaction rate due to mass transport phenomena. The apparent activation energies were higher for the systems based on agar, independently of the microemulsion used, and lower for the systems based on AOT microemulsions, independently of the polymer used.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1007/s10529-008-9734-1-
heal.identifier.secondary<Go to ISI>://000258556000018-
heal.identifier.secondaryhttp://www.springerlink.com/content/n648616406176478/fulltext.pdf-
heal.journalNameBiotechnology Lettersen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2008-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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