Reaction of a triazolinedione with simple alkenes. Isolation and characterization of hydration products
| dc.contributor.author | Syrgiannis, Z. | en |
| dc.contributor.author | Koutsianopoulos, F. | en |
| dc.contributor.author | Muir, K. W. | en |
| dc.contributor.author | Elemes, Y. | en |
| dc.date.accessioned | 2015-11-24T16:46:03Z | |
| dc.date.available | 2015-11-24T16:46:03Z | |
| dc.identifier.issn | 0040-4039 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9022 | |
| dc.rights | Default Licence | - |
| dc.subject | ene reactions | en |
| dc.subject | triazolinediones | en |
| dc.subject | solvent addition | en |
| dc.subject | water addition | en |
| dc.subject | thermodynamic parameters | en |
| dc.subject | x-ray | en |
| dc.subject | ene reaction | en |
| dc.subject | n-phenyltriazolinedione | en |
| dc.subject | singlet oxygen | en |
| dc.subject | benzyltriphenylphosphonium peroxymonosulfate | en |
| dc.subject | thiols | en |
| dc.subject | disulfides | en |
| dc.subject | oxidation | en |
| dc.subject | solvent | en |
| dc.subject | mechanism | en |
| dc.subject | efficient | en |
| dc.title | Reaction of a triazolinedione with simple alkenes. Isolation and characterization of hydration products | en |
| heal.abstract | The reaction of N-phenyltriazolinedione with three simple alkyl-substituted alkenes in water/alcohol or water/acetone solution was found to give a mixture or the corresponding ene and water addition products. The new hydration products were characterized by spectroscopy, and in one case, also by X-ray diffraction analysis. Thermodynamic parameters were determined for the reactions involving 2-methylbut-2-ene, TriME, and 2,3-dimethylbut-2-ene, TetraMe, in accordance with an 'S(N)2-like', nucleophilic attack on a closed aziridinium imide (At) intermediate by water. (C) 2008 Elsevier Ltd. All rights reserved. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | DOI 10.1016/j.tetlet.2008.10.150 | - |
| heal.identifier.secondary | <Go to ISI>://000263152800007 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S0040403908020601/1-s2.0-S0040403908020601-main.pdf?_tid=f6cacca45afcda900d6ec87b257ff93f&acdnat=1333029130_9fb5da02b79327d3630a6785f23ebdb5 | - |
| heal.journalName | Tetrahedron Lett | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2009 | - |
| heal.publisher | Elsevier | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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