Formation of PPh2C6F5 through phosphido platinum and/or palladium(III) intermediates
| dc.contributor.author | Ara, I. | en |
| dc.contributor.author | Chaouche, N. | en |
| dc.contributor.author | Fornies, J. | en |
| dc.contributor.author | Fortuno, C. | en |
| dc.contributor.author | Kribii, A. | en |
| dc.contributor.author | Tsipis, A. C. | en |
| dc.date.accessioned | 2015-11-24T16:38:11Z | |
| dc.date.available | 2015-11-24T16:38:11Z | |
| dc.identifier.issn | 0276-7333 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8012 | |
| dc.rights | Default Licence | - |
| dc.subject | bridging diphenylphosphido ligands | en |
| dc.subject | palladium(ii)-platinum(ii) pentafluorophenyl complexes | en |
| dc.subject | stereoselective oxidative addition | en |
| dc.subject | density-functional theory | en |
| dc.subject | ray crystal-structures | en |
| dc.subject | molecular-structure | en |
| dc.subject | electronic-structures | en |
| dc.subject | pd-c6f5 bonds | en |
| dc.subject | c bond | en |
| dc.subject | bu-t | en |
| dc.title | Formation of PPh2C6F5 through phosphido platinum and/or palladium(III) intermediates | en |
| heal.abstract | The two-electron oxidation reactions of the neutral [(C6F5)(2)M(mu-PR2)(2)M'(NCCH3)(2)] (M = M' = Pt or Pd, M = Pt, M' = Pd) complexes using I-2 as oxidant have been investigated by experimental (R = Ph) and electronic structure calculation methods (R = H). It was found that a reductive coupling of PR, and C6F5 takes place along the reaction pathway for all oxidized complexes. The most salient structural features of the [(C6F5)(2)Pt(mu-PR2)(2)Pd(C6F5)(2)](2-), [(C6F5)(2)Pd(mu-PR2)(2)Pd(acac)](-), and [(C6F5)(2)Pt(mu-PR2)(2)PtI2] complexes (experimental R = Ph) are reproduced very well by the B3LYP/lan12dz calculations (R = H). | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | Doi 10.1021/Om0508029 | - |
| heal.identifier.secondary | <Go to ISI>://000235691500005 | - |
| heal.identifier.secondary | http://pubs.acs.org/doi/abs/10.1021/om0508029 | - |
| heal.journalName | Organometallics | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2006 | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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