One-pot thermally chemocontrolled double Diels-Alder strategies. A route to [4+2] functionalisation/[4+2] derivatization of C-60
| dc.contributor.author | Markoulides, M. S. | en |
| dc.contributor.author | Ioannou, G. I. | en |
| dc.contributor.author | Manos, M. J. | en |
| dc.contributor.author | Chronakis, N. | en |
| dc.date.accessioned | 2015-11-24T16:43:20Z | |
| dc.date.available | 2015-11-24T16:43:20Z | |
| dc.identifier.issn | 2046-2069 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8687 | |
| dc.rights | Default Licence | - |
| dc.subject | efficient preparation | en |
| dc.subject | electron-transfer | en |
| dc.subject | fullerene c-60 | en |
| dc.subject | pi-donors | en |
| dc.subject | chemistry | en |
| dc.subject | rongalite | en |
| dc.subject | derivatives | en |
| dc.subject | anthracene | en |
| dc.subject | expansion | en |
| dc.subject | adducts | en |
| dc.title | One-pot thermally chemocontrolled double Diels-Alder strategies. A route to [4+2] functionalisation/[4+2] derivatization of C-60 | en |
| heal.abstract | The one-pot double Diels-Alder reactions of 3,4-di(methylene)tetrahydrothiophene-1,1-dioxide using temperature as the only chemocontrol element are described. Zn-dust promoted the 1,4-debromination of 3,4-bis(bromomethyl)-2,5-dihydrothiophene-1,1-dioxide in 5-nonanone, under MW conditions, followed by a Diels-Alder reaction, an SO2 extrusion step and a second Diels-Alder reaction. This approach was applied successfully in double [4 + 2] cycloadditions using the same or two different dienophiles to afford the corresponding Diels-Alder products in excellent yields. An elegant and practical method for [4 + 2] functionalisation/[4 + 2] derivatization of C-60 was achieved in a one-pot manner via the formation of a new reactive C-66 dienic intermediate. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | Doi 10.1039/C3ra23327h | - |
| heal.identifier.secondary | <Go to ISI>://000315905400040 | - |
| heal.identifier.secondary | http://pubs.rsc.org/en/Content/ArticleLanding/2013/RA/c3ra23327h | - |
| heal.journalName | Rsc Advances | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2013 | - |
| heal.publisher | Royal Society of Chemistry | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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