Synthesis of N-(Dipheylmethyl)Anilines and P-(Diphenylmethyl)Anilines - Esr Study of Their Photofragmentation
| dc.contributor.author | Siskos, M. G. | en |
| dc.contributor.author | Garas, S. K. | en |
| dc.contributor.author | Zarkadis, A. K. | en |
| dc.contributor.author | Bokaris, E. P. | en |
| dc.date.accessioned | 2015-11-24T16:49:17Z | |
| dc.date.available | 2015-11-24T16:49:17Z | |
| dc.identifier.issn | 0009-2940 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9460 | |
| dc.rights | Default Licence | - |
| dc.subject | benzenamine derivatives, synthesis of | en |
| dc.subject | rearrangement, hofmann-martius | en |
| dc.subject | diphenylmethyl radicals | en |
| dc.subject | esr measurements | en |
| dc.subject | endor measurements | en |
| dc.subject | single electron-transfer | en |
| dc.subject | hindered free-radicals | en |
| dc.subject | spin resonance | en |
| dc.subject | chemistry | en |
| dc.subject | amines | en |
| dc.subject | bond | en |
| dc.subject | pair | en |
| dc.title | Synthesis of N-(Dipheylmethyl)Anilines and P-(Diphenylmethyl)Anilines - Esr Study of Their Photofragmentation | en |
| heal.abstract | The reaction of N-substituted anilines 2 with diphenylmethyl halides 1 at room temperature in the presence of AlCl3 affords p-substituted derivatives 3 in good yields according to an electrophilic aromatic substitution. In contrast, aniline itself is only converted to the N-substituted compounds 4. A novel rearrangement from Ph3C-NHPh (4c) to p-(triphenylmethyl)aniline (5) is described. Unexpected photofragmentations of 4a, b are studied by using ESR and ENDOR spectroscopy; e.g., irradiation of 4b with quartz- or pyrex-filtered light leads to the formation of the radicals Ph2C-SiMe3 (7b) and Ph2C - NHPh (6) respectively, following selective cleavage of the C - N and C - Si bond. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | DOI 10.1002/cber.19921251120 | - |
| heal.identifier.secondary | <Go to ISI>://A1992KC74600019 | - |
| heal.identifier.secondary | http://onlinelibrary.wiley.com/store/10.1002/cber.19921251120/asset/19921251120_ftp.pdf?v=1&t=hmsubuuv&s=a106a3cdc22eab2b0249c65c898128788be30c62 | - |
| heal.journalName | Chemische Berichte-Recueil | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 1992 | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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