Surface-activation processes and ion-solid interactions during the nucleation and growth of ultra-thin amorphous carbon films

dc.contributor.authorPatsalas, P.en
dc.contributor.authorLogothetidis, S.en
dc.contributor.authorKennou, S.en
dc.contributor.authorGravalidis, C.en
dc.date.accessioned2015-11-24T17:38:57Z
dc.date.available2015-11-24T17:38:57Z
dc.identifier.issn0040-6090-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/14567
dc.rightsDefault Licence-
dc.subjectcarbonen
dc.subjectgrowth mechanismen
dc.subjectsurface compositionen
dc.subjectplasma processing and depositionen
dc.subjectdeposition mechanismen
dc.subjectenergyen
dc.subjectmodelen
dc.subjectxpsen
dc.titleSurface-activation processes and ion-solid interactions during the nucleation and growth of ultra-thin amorphous carbon filmsen
heal.abstractAmorphous carbon (a-C) films have been grown by processes using Ar+ or C+ ions. The films hybridization states were evaluated by Auger electron spectroscopy, X-ray photoelectron spectroscopy and X-ray reflectivity. It was found that the films grown using C+ (Ar+) exhibit a sp(2) (sp(3)) surface, while the deeper monolayers are sp(3) (mixed sp(3)-sp(2)) bonded. These results were compared with simulations of the ion-solid interactions and the results of a phenomenological model which takes into account the balance between the surface and bulk processes. We found two mechanisms of spa formation: on the surface and in the bulk of a-C. We conclude that at medium energy (> 100 eV) the surface effects are negligible (for both C+ and Ar+), while the surface processes dominate when low-energy (similar to40 eV) Ar+ ions are used. (C) 2002 Elsevier Science B.V. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDoi 10.1016/S0040-6090(02)01265-8-
heal.identifier.secondary<Go to ISI>://000182500500043-
heal.journalNameThin Solid Filmsen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2003-
heal.publisherElsevieren
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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