Substrate-induced diastereoselectivity in the dimethyldioxirane epoxidation of simple alkenes and dienes
| dc.contributor.author | Asouti, A. | en |
| dc.contributor.author | Hadjiarapoglou, L. P. | en |
| dc.date.accessioned | 2015-11-24T16:48:45Z | |
| dc.date.available | 2015-11-24T16:48:45Z | |
| dc.identifier.issn | 0936-5214 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9360 | |
| dc.rights | Default Licence | - |
| dc.subject | dimethyldioxirane | en |
| dc.subject | epoxidation | en |
| dc.subject | diasteroselectivity | en |
| dc.subject | regioselectivity | en |
| dc.subject | hydrogen-peroxide | en |
| dc.subject | transition-state | en |
| dc.subject | natural product | en |
| dc.subject | oxygen-transfer | en |
| dc.subject | dioxiranes | en |
| dc.subject | oxidation | en |
| dc.subject | chemistry | en |
| dc.subject | ethers | en |
| dc.subject | methyl(trifluoromethyl)dioxirane | en |
| dc.subject | (+)-pramanicin | en |
| dc.title | Substrate-induced diastereoselectivity in the dimethyldioxirane epoxidation of simple alkenes and dienes | en |
| heal.abstract | Various alkenes and dienes, such as (R)- or (S)-limonene 2, 2-carene 6, 3-carene 8, (R)-alpha -pinene 10, (S)-alpha -pinene 12, and endo-dicyclopentadiene 14 were transformed into the corresponding mono- and bis-epoxides by epoxidation with dimethyldioxirane (as an acetone solution). The selectivity observed in these epoxidations is explained by the assumption of hydrogen bonding between bridge protons and the dioxirane. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.secondary | <Go to ISI>://000172596400006 | - |
| heal.identifier.secondary | https://docs.google.com/file/d/0BxfLht5wJUEIMzIyZDQ0ZWItNmYxOS00ZTkwLThlZTktZmMzNDk5ZDNmOWYy/edit?pli=1&hl=en | - |
| heal.journalName | Synlett | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2001 | - |
| heal.publisher | Georg Thieme Verlag | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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