Insights into the N,N-diacylation reaction of 2-aminopyrimidines and deactivated anilines: an alternative N-monoacylation reaction
| dc.contributor.author | V. Theodorou, | en |
| dc.contributor.author | M. Gogou, | en |
| dc.contributor.author | A. Giannousi, | en |
| dc.contributor.author | K. Skobridis | en |
| dc.date.accessioned | 2015-11-24T16:40:09Z | |
| dc.date.available | 2015-11-24T16:40:09Z | |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8237 | |
| dc.rights | Default Licence | - |
| dc.subject | N,N-Diacylation, N-monoacylation, 2-aminopyrimidine, aminopyrazine, deactivated anilines, Imatinib analogues | en |
| dc.title | Insights into the N,N-diacylation reaction of 2-aminopyrimidines and deactivated anilines: an alternative N-monoacylation reaction | en |
| heal.abstract | During the N-benzoylation reaction for the synthesis of N-substituted aminopyrimidines, an undesired N,N-diacylation reaction took place. The extension of this N-acylation reaction to a series of several 2-aminopyrimidines, aminopyrazines and highly deactivated anilines produced analogous results. The possible mechanism responsible for that behavior is investigated and an advantageous alternative procedure for the clean formation of the desired amides is suggested. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.secondary | http://quod.lib.umich.edu/a/ark/5550190.p008.209/1 | - |
| heal.journalName | Arkivoc (Archive for Organic Chemistry) | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2013 | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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