Mild and Rapid Method for the Generation of ortho-(Naphtho)quinone Methide Intermediates
| dc.contributor.author | Shaikh, A. K. | en |
| dc.contributor.author | Cobb, A. J. A. | en |
| dc.contributor.author | Varvounis, G. | en |
| dc.date.accessioned | 2015-11-24T16:41:52Z | |
| dc.date.available | 2015-11-24T16:41:52Z | |
| dc.identifier.issn | 1523-7060 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8482 | |
| dc.rights | Default Licence | - |
| dc.subject | o-quinone methides | en |
| dc.subject | diels-alder reactions | en |
| dc.subject | aqueous-solution | en |
| dc.subject | biomimetic synthesis | en |
| dc.subject | efficient method | en |
| dc.subject | cross-linking | en |
| dc.subject | derivatives | en |
| dc.subject | tautomerization | en |
| dc.subject | photogeneration | en |
| dc.subject | (+/-)-alboatrin | en |
| dc.title | Mild and Rapid Method for the Generation of ortho-(Naphtho)quinone Methide Intermediates | en |
| heal.abstract | A new mild method has been devised for generating o-(naphtho)quinone methides via fluoride-induced desilylation of silyl derivatives of o-hydroxybenzyl(or 1-naphthylmethyl) nitrate. The reactive o-(naphtho)quinone methide intermediates were trapped by C, O, N, and S nucleophiles and underwent "inverse electron-demand" hetero-Diels-Alder reaction with dienophiles to give stable adducts. The method has useful potential application in natural product synthesis and drug research. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | Doi 10.1021/Ol203196n | - |
| heal.identifier.secondary | <Go to ISI>://000299238600041 | - |
| heal.identifier.secondary | http://pubs.acs.org/doi/pdfplus/10.1021/ol203196n | - |
| heal.journalName | Org Lett | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2012 | - |
| heal.publisher | American Chemical Society | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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